Sodium silicate is the common name for compounds with the formula Na2(SiO2)nO. A well-known member of this series is sodium metasilicate, Na2SiO3. Also known as waterglass or liquid glass, these materials are available in aqueous solution and in solid form. The pure compositions are colourless or white, but commercial samples are often greenish or blue owing to the presence of iron-containing impurities.
They are used in cements, passive fire protection, textile and lumber processing, refractories, and automobiles. Sodium carbonateand silicon dioxide react when molten to form sodium silicate and carbon dioxide:
Anhydrous sodium silicate contains a chain polymeric anion composed of corner-shared {SiO4} tetrahedral, and not a discrete SiO32− ion.
In industry, the various grades of sodium silicate are characterized by their SiO2:Na2O weight ratio (weight ratios can be converted to molar ratios by multiplication with 1.032), which can vary between 2:1 and 3.75:1. Grades with this ratio below 2.85:1 are termed alkaline. Those with a higher SiO2:Na2O ratio are described as neutral.
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Disodium oxosilanediolate (IUPAC Name); Disodium salt oxo-silanediolate; sodium metasilicate